Potential energy curves for electron beam excitation of RbXe+ excimer
โ Scribed by K. Balasubramanian; Ping Yi Feng
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 502 KB
- Volume
- 214
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Complete active space self-consistent field followed by confguration interaction and relativistic configuration interaction calculations are carried out on the potential energy curves of (XeRb)+ arising from Xe( 'So) +Rb+ ('So), Xef(2P,,2) +Rb(2S,,2), Xe+ ('PI12) +Rb( 'SI12), and Xe*('P) t Rb+ ('S) electronic states. Spectroscopic constants and potential energy curves thus ob tained are used to interpret the fluorescence from ionic (Xe-Rb)+ species excited by an electron beam. The nature of the various electronic states of (XeRb)+ is analyzed,
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