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Potential energy curves for electron beam excitation of RbXe+ excimer

โœ Scribed by K. Balasubramanian; Ping Yi Feng


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
502 KB
Volume
214
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Complete active space self-consistent field followed by confguration interaction and relativistic configuration interaction calculations are carried out on the potential energy curves of (XeRb)+ arising from Xe( 'So) +Rb+ ('So), Xef(2P,,2) +Rb(2S,,2), Xe+ ('PI12) +Rb( 'SI12), and Xe*('P) t Rb+ ('S) electronic states. Spectroscopic constants and potential energy curves thus ob tained are used to interpret the fluorescence from ionic (Xe-Rb)+ species excited by an electron beam. The nature of the various electronic states of (XeRb)+ is analyzed,


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