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Potential Constants of Iodine Heptafluoride

โœ Scribed by G. Nagarajan

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
470 KB
Volume
71
Category
Article
ISSN
0037-9646

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โœฆ Synopsis

Abstract

A vibrational analysis has been made for the XY~7~ type molecules and radicals which have the pentagonal bipyramidal structure belonging to the symmetry point group D~5__h__~. An orthonormalized set of symmetry coordinates satisfying the transformation properties has been constructed for XY~7~ type molecules. The elements of F and G matrices have been worked out and from these matrices the secular equations for the various irreducible representations have been deduced by means of Wilson's group theoretical method. A potential function consisting of the ordinary valence force terms and central force terms has been adopted for the evaluation of potential constants for Iodine heptafluoride.

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On the basis of Wilson's group theoretical method, normal coordinate analysis for XYSZ type molecules having Cst symmetry has been carried out. Following Dennison, the anharmorticity factors have been calculated using the spectral data of silyl fluoride, silyl-da fluoride, silyl chloride, silyl-ds c