Using the observed Raman fundamental frequencies of GeHCb and GeHBra the potential constants on the basis of Wilson's group theoretical method and the thermodynamic properties upto a rigid rotator, harmonic oscillator approximation were calculated. The Raman spectra of various Germanium compounds h
Potential Constants and Thermodynamic Properties of Some Silyl Halides
โ Scribed by G. Nagarajan
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 402 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0037-9646
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โฆ Synopsis
On the basis of Wilson's group theoretical method, normal coordinate analysis for XYSZ type molecules having Cst symmetry has been carried out. Following Dennison, the anharmorticity factors have been calculated using the spectral data of silyl fluoride, silyl-da fluoride, silyl chloride, silyl-ds chlo-
๐ SIMILAR VOLUMES
## Abstract Potential constants of eleven molecules and eleven ions of the XY~4~ type with the symmetry point group Td have been evaluated on the basis of Wilson's group theoretical method. The thermodynamic properties for the eleven molecules have also been calculated for a rigid rotator, harmonic
T is the temperature in degrees Kelvin; the other quantities are in cal. deg.-1. mole-1 and E: is the energy of one mole of perfect gas at absolute zero temperature. n \* \* T is the temperature in degrees Kelvin; the other quantities are in cal. deg.-l. mole-1 and E: is the energy of one mole of pe