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Possible evidence for the existence of H2Ar molecule in solid H2-Ar mixtures

✍ Scribed by Simon S. Cohen


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
196 KB
Volume
18
Category
Article
ISSN
0009-2614

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✦ Synopsis


Two special lattice excitations were observed by Welsh et al. in rare-gas crystals doped with hydrogen molecules.

One of these two modes was assigned by Welsh et al. to a localized mode of the hydrogen molecule occupying T. substitutional lattice site. The other lattice absorption is attributed here to resonance mode of the "cornpIes" mo!ecuIc H2Ar.


πŸ“œ SIMILAR VOLUMES


Rate constant for H+O2β†’O+OH by laser abs
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## Therateconstantexpression, k&.0x 1014exp( -95 kJ/RT) cm3 mol-' s-t, for H+O ,+O + OH was determined from cw laser absorption spectroscopic measurements of OH radical concentration growth rates in rich Hz-OZ-Ar mixtures heated to temperatures between 1900 and 2650 K in reflected shock waves.

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Emissions at 450 nm and 4.27 ~sm have been measured when a vaxiety of mixtures containing H 2, CO. either 02 or NaO, and Ar were heated behind reflected shock waves to temperatures of 2000-2850 K and total concentrations near 5 x 101| molecule/era 3. These emissions were used to obtain absolute con