In the crystal structure of the polymeric title compound, [Co(C~10~H~8~O~5~)(C~10~H~8~N~2~)(H~2~O)]~__n__~, the Co^II^ atom is __O__,__O__′-chelated by the aromatic carboxylate end of the 3-(4-carboxylatophenoxy)propionate dianion, and is covalently bonded (through one O atom) by the aliphatic carbo
Poly[(μ4-3-pyridylphosphonato-κ4-N:O:O′:O′′)cobalt(II)]
✍ Scribed by Wasson, Anna E. ;LaDuca, Robert L.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 351 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, {[Co(C 8 H 4 O 5 )(C 12 H 8 N 2 )]ÁH 2 O} n , is isostructural with its manganese analog [Skakle, Foreman & Plater (2001). Acta Cryst. E57, m373±m375]. The asymmetric unit consists of one Co atom, one 1,10-phenanthroline ligand bound in a bidentate manner, one hydroxyisophthalate
In the title compound, {[Co(C~8~H~4~O~5~)(C~10~H~8~N~2~)]·2H~2~O]}~__n__~ or {[Co(OH-BDC)(2,2′-bipy)]·2H~2~O]}~__n__~ (where OH-H~2~BDC is 5-hydroxyisophthalic acid and 2,2′-bipy is 2,2′-bipyridine), the Co atoms are chelated by two N atoms from the 2,2′-bipy ligand and by four O atoms from OH-BDC l
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.030 wR factor = 0.074 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.