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Poly[[μ2-trans-1,2-di-4-pyridylethylene]hexa-μ2-oxido-nickel(II)divanadate(V)]

✍ Scribed by Wang, Chong-Chen

Book ID
104491466
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
586 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The structure of the title compound, [NiV 2 O 6 (C 12 H 10 N 2 )] n , is composed of corner-sharing [V 2 O 6 ] 2À chains along the c axis, with the [Ni(bpe)] 2+ (bpe = trans-1,2-di-4-pyridylethylene) units covalently attached to every V site through O atoms. The Ni atom is octahedrally coordinated by two pyridyl N atoms from two different bpe ligands, and four O atoms from four different VO 4 tetrahedra. All the C and H atoms are disordered over two positions each; the site occupancy factors are ca 0.55 and 0.45.

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