Poly[tetra-μ2-azido-di-μ2-4,4′-bipyridine-sodium(I)iron(III)]
✍ Scribed by Näther, Christian ;Greve, Jan ;Jeß, Inke
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 179 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the crystal structure of {[Ag(BrO 3 )(C 10 H 8 N 2 )]Á2.5H 2 O} n , the Ag atom is coordinated by the N atoms of two different spacer donor ligands [AgÐN = 2.147 (2) and2.152 (2) A Ê , and NÐAgÐN = 172.0 (1) ], but is connected only weakly to the O atoms of two different bromate counter-ions [AgÐ
The title compound, (C 8 H 20 N)[Re 2 (C 5 H 4 NO)(CH 3 O) 2 (CO) 6 ], was obtained from a ligand-substitution reaction of (Et 4 N)[Re 2 (OMe) 3 (CO) 6 ] with 2-hydroxypyridine in methanol solvent. Both Re centers are in an approximate octahedral geometry.