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catena-Poly­[[bromatosilver(I)-μ-4,4′-bi­pyridine] 2.5-hydrate]

✍ Scribed by Ren, Chun-Xia ;Cheng, Li ;Chen, Xiao-Ming ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
275 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of {[Ag(BrO 3 )(C 10 H 8 N 2 )]Á2.5H 2 O} n , the Ag atom is coordinated by the N atoms of two different spacer donor ligands [AgÐN = 2.147 (2) and2.152 (2) A Ê , and NÐAgÐN = 172.0 (1) ], but is connected only weakly to the O atoms of two different bromate counter-ions [AgÐO = 2.877 (3) and 2.972 (3) A Ê , and OÐAgÐO = 162.3 (1) ]; the coordination geometry of the Ag atom is approximately planar. The (C 10 H 8 N 2 )Ag chains, which propagate along [101], are cross-linked in the b direction by bromate anions and AgÁ Á ÁAg [3.3197 (6) A Ê ] interactions, thus forming sheets.

📜 SIMILAR VOLUMES

catena-Poly­[[silver(I)-μ-4,4′-bi­pyridi
catena-Poly­[[silver(I)-μ-4,4′-bi­pyridine-κ2N:N′] perchlorate]
✍ Wang, Li-Shi ;Zhang, Jin-Feng ;Yang, Shi-Ping 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 140 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.133 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.