Polysilyl radicals: EPR study of the formation and decomposition of star polysilanes
โ Scribed by Y. Apeloig; D. Bravo-Zhivotovskii; M. Yuzefovich; M. Bendikov; A. I. Shames
- Publisher
- Springer Vienna
- Year
- 2000
- Tongue
- English
- Weight
- 640 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0937-9347
No coin nor oath required. For personal study only.
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Recent chemical, electrochemical and electron spin resonance studies of halogenated nitroaromatics have shown that loss of anionic substituents is a frequently observed pathway for anion radical decomposition 1 -14. The neutral radicals which result from loss of the anionic substituents react by num
The relative yields of cyclohexyl radical in pulse-irradiated liquid cyclohexane and cyclohexane solutions containing negatwe (C02) and positive charge scavengers (cis-and trans-decalin) are measured via time-resolved EPR. Charge scavenging has a negligible effect on radical production. A mechanism