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Polypyridyl Ruthenium(II) Complexes with Tetrazolate-Based Chelating Ligands. Synthesis, Reactivity, and Electrochemical and Photophysical Properties

✍ Scribed by Stagni, Stefano; Orselli, Enrico; Palazzi, Antonio; De Cola, Luisa; Zacchini, Stefano; Femoni, Cristina; Marcaccio, Massimo; Paolucci, Francesco; Zanarini, Simone


Book ID
126940392
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
428 KB
Volume
46
Category
Article
ISSN
0020-1669

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The novel tridentate 2,2':6',2''-terpyridine ligand (1) in which the metalbinding domain is directly attached to a methanofullerene C 60 unit was incorporated into ruthenium-based diads and triads that may undergo photoinduced charge separation. In this paper, the new complexes are compared with mor