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Polynuclear copper(II) complexes with oxygen bridges: The relationship betweeen magnetic properties and structure

✍ Scribed by J.A. Bertrand; J.A. Kelley

Book ID
114041407
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
801 KB
Volume
4
Category
Article
ISSN
0020-1693

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Polynuclear MnII Complexes with Chloroac
Polynuclear MnII Complexes with Chloroacetate Bridge − Syntheses, Structure, and Magnetic Properties
✍ Gema Fernández; Montserrat Corbella; José Mahía; Miguel A. Maestro 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB 👁 1 views

Three new polynuclear Mn II complexes with chloroacetate bridges were obtained and characterized by X-ray diffraction: 2), and [Mn(µ-ClCH 2 COO) 2 (phen)] n (3). The Mn•••Mn distance for 1 (3.624 A ˚) is smaller than for 2 (4.613 A ˚) and 3 (4.530 A ˚); this is in agreement with the number of carbox