Poly[(N,N-dimethylacetamide)(μ5-naphthalene-1,4-dicarboxylato)cadmium(II)]
✍ Scribed by Zhang, Rong-Chang
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 346 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Cd(C 12 H 6 O 4 )(C 4 H 9 NO)] n , each Cd II atom is coordinated by six O atoms from four naphthalene-1,4-dicarboxylate (L) ligands (three monodentate and one bidentate) and one O-bonded N,N-dimethylacetamide molecule in a very distorted octahedral coordination. Each L ligand bridges five Cd II atoms, generating a distinctive threedimensional coordination polymer.
📜 SIMILAR VOLUMES
In the title compound, [Gd~2~(C~8~H~4~O~4~)~3~(C~3~H~7~NO)~2~(H~2~O)~2~]~__n__~, the central Gd^III^ atom is nine-coordinated by seven O atoms from benzene-1,4-dicarboxylate (1,4-BDC) ligands, one dimethylformamide and one water molecule in a distorted tricapped trigonal–prism coordination. The 1,4-
In the molecule of the title compound, [CdCu~2~(C~8~H~3~O~5~)~2~(H~2~O)~2~]~__n__~, each 2-oxidobenzene-1,3-dicarboxylate trianion is bonded to two Cu atoms through O atoms of the carboxylates and the deprononated hydroxy group in chelating mode, forming [Cu~2~(C~8~H~3~O~5~)~2~]^2−^ units. A pair of
2 N,N 0 0 0 )cadmium(II)]-l 3pyridine-3,4-dicarboxylato-j 5 N:O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0
Single-crystal X-ray study T = 294 K Mean (C-C) = 0.004 A R factor = 0.044 wR factor = 0.125 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.