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Poly[(nitrato-κO)tris(μ3-1H-1,2,4-triazolato)dizinc(II)]: a three-dimensional coordination polymer

✍ Scribed by Ellsworth, Joseph M. ;Smith, Mark D. ;Loye, Hans-Conrad zur

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 952 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807049574

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✦ Synopsis

In the title compound, [Zn~2~(C~2~H~2~N~3~)~3~(NO~3~)], there are two unique Zn atoms, both with site symmetry m. One forms a ZnN~3~O tetrahedron and the other a ZnN~6~ octahedron. One and a half 1__H__-1,2,4-triazolate ligands, with the half-ligand located on a mirror plane, and a disordered nitrate anion complete the asymmetric unit of the structure. The polymeric connectivity is three-dimensional.

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