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A one-dimensional herring-bone coordination polymer, catena-poly[[bis­(1H-imidazole-κN3)zinc(II)]-μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ2O1:O3]

✍ Scribed by Zhang, Hong-Tao ;Li, Yi-Zhi ;Xu, Li ;You, Xiao-Zeng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
214 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn(C 8 H 3 NO 6 )(C 3 H 4 N 2 ) 2 ] n , each Zn II atom is four-coordinated and bridged by a 5-nitrobenzene-1,3dicarboxylate ligand to form a one-dimensional herring-bone chain. Interchain hydrogen bonds connect the chains to produce a two-dimensional double-sheet layer. In the crystal structure, all double-sheet layers are stabilized via interlayer interactions between adjacent benzene rings.

metal-organic papers m1728 Zhang et al. [Zn(C 8 H 3 NO 6 )(C 3 H 4 N 2 ) 2 ]

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✍ Wang, Li-Bin ;Li, Xiu-Mei ;Wang, Qing-Wei ;Liu, Bo 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 242 KB

In the title compound, [Cd(C~8~H~4~O~4~)(C~3~H~4~N~2~)~2~(H~2~O)]~__n__~, the Cd center is six-coordinated by three O atoms from two benzene-1,3-dicarboxylate dianions, two N atoms from two imidazole ligands and one water molecule in a distorted octahedral geometry. The benzene-1,3-dicarboxylate dia