The radical polymerization of N-(2-hydroxypropyl)methacrylamide was investigated kinetieally. The hydrophilic character of the polymerization medium was found to affect the rate of decomposition of the initiator [2,2'-azobis(methyl isobutyrate)] and the course of primary radical termination. The pre
Poly[N-(2-hydroxypropyl)methacrylamide]—iii: Crosslinking copolymerization
✍ Scribed by J. Kopecék; H. Baźilová
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 388 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
The crosslinking copolymerization of N-(2-hydroxypropyl)methacrylamide with ethylene-bismethacrylamide or methylene-bis-acrylamide was investigated. The kinetic course of copolymerization was characterized and interpreted in terms of diffusion-controlled reactions during the copolymerization. The dependence of the properties of the polymer thus obtained on the reaction conditions was characterized by the interaction parameter polymer-water, by the modulus of elasticity and by the concentration of elastically effective chains. The process of three-dimensional network formation was also described.
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