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Polymorphism of the mixed tin fluoride Sn2F6

✍ Scribed by J. Grannec; L. Fournès; P. Lagassié; P. Hagenmuller; J.C. Cousseins

Book ID
113188281
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
305 KB
Volume
25
Category
Article
ISSN
0025-5408

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Tin(II) aminoalkoxides and heterobimetal
Tin(II) aminoalkoxides and heterobimetallic derivatives: the structures of Sn6(O)4(dmae)4, Sn6(O)4(OEt)4 and [Sn(dmae)2Cd(acac)2]2
✍ Nathan Hollingsworth; Graeme A. Horley; Muhammed Mazhar; Mary F. Mahon; Kieran C 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 2 views

## Abstract Tin(II) methoxide reacts with __N__,__N__′‐dimethylaminoethanol (dmaeH) to yield Sn(dmae)~2~ (1) along with small amounts of the hydrolysis product Sn~6~(O)~4~(dmae)~4~ (2). The geometrically more regular iso‐structural cage Sn~6~(O)~4~(OEt)~4~ (3) was obtained as the only tractable pro