Far-ix. spectra of crystalline isotactic polypropylene (IPP) in its various polymorphic forms have been recorded over the range 500-100 cm-'. Differences in the spectra, in particular the splitting of certain A line-group modes, reflect the environments of isolated IPP chains within the particular u
Polymorphism of crystalline polypropylene
β Scribed by E.J. Addink Miss; J. Beintema
- Book ID
- 103346458
- Publisher
- Elsevier Science
- Year
- 1961
- Tongue
- English
- Weight
- 715 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0032-3861
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Abstraet~Conformational energy calculations have been performed on two crystalline polymorphic forms of syndiotactic polypropylene. A chain conformation having the helicoidal s(2/1)2 symmetry has been obtained for the form of the polymer having chain axis c = 7.40 A.. A chain conformation having the
## Abstract A number of commercial and experimental samples of crystalline polypropylene were fractionated by sand column solvent gradient elution techniques. Two different solventβnonsolvent systems were studied under several sets of experimental conditions. Deposition of polymer upon the sand fro