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Polymorphism in an Aqua-Bridged, Dinuclear 2-Nitrobenzoate Complex of Cobalt(II)

✍ Scribed by Anirban Karmakar; Rupam J. Sarma; Jubaraj B. Baruah


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
222 KB
Volume
2007
Category
Article
ISSN
1434-1948

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An end-off type acyclic ligand with four methoxyethyl chelating arms, 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4methylphenol [H(bomp)], formed dinuclear cobalt(II) complexes [Co 2 (bomp)(MeCO 2 ) 2 ]BPh 4 (1) and [Co 2 (bomp)-(PhCO 2 ) 2 ]BPh 4 (2). X-ray analysis revealed that complex 1β€’CHCl 3 conta