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Dinuclear Cobalt(II) Complexes of an Acyclic Phenol-Based Dinucleating Ligand with Four Methoxyethyl Chelating Arms − First Magnetic Analyses in an Axially Distorted Octahedral Field

✍ Scribed by Hiroshi Sakiyama; Rie Ito; Hitoshi Kumagai; Katsuya Inoue; Masatomi Sakamoto; Yuzo Nishida; Mikio Yamasaki

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
135 KB
Volume
2001
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES

Dinuclear Cobalt(II) Complexes of an Acy
Dinuclear Cobalt(II) Complexes of an Acyclic Phenol-Based Dinucleating Ligand with Four Methoxyethyl Chelating Arms − First Magnetic Analyses in an Axially Distorted Octahedral Field
✍ Hiroshi Sakiyama; Rie Ito; Hitoshi Kumagai; Katsuya Inoue; Masatomi Sakamoto; Yu 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 338 KB

An end-off type acyclic ligand with four methoxyethyl chelating arms, 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4methylphenol [H(bomp)], formed dinuclear cobalt(II) complexes [Co 2 (bomp)(MeCO 2 ) 2 ]BPh 4 (1) and [Co 2 (bomp)-(PhCO 2 ) 2 ]BPh 4 (2). X-ray analysis revealed that complex 1•CHCl 3 conta