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Polymers derived from 2-phenyl-1,1,1,3,3,3-hexafluoropropan-2-ol and its derivatives

✍ Scribed by Patrick E. Cassidy; Tejraj M. Aminabhavi; V.Sreenivasulu Reddy; John W. Fitch III


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
723 KB
Volume
31
Category
Article
ISSN
0014-3057

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✦ Synopsis


Over the past 25 yr several classes of polymers (epoxy resins, polyurethanes, polyacrylates etc.) derived from aromatic monomers bearing -C(CF,),OH groups have been developed. These materials have exceptional heat, light and chemical resistance in addition to low surface energy, low water absorption and low dielectric constant. They have been suggested for use in a variety of ways such as biological anti-fouling materials, dental composites, cladding for optical fibers, textile impregnants and marine coatings.


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## Abstract The triazaphosphole __1__ adds sulfur along with HCl or H~2~S to yield, respectively, the dihydrotriazaphosphole thiochloride __4__ and sesquisulfide __5__ (two diastereomers). In pyridine solution, __1__ adds sulfur alone to yield the trimer of a triazaphosphole monosulfide __7__. Its