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Polymerization of racemic methylthiirane using a chiral initiator prepared with a diastereoisomeric 1,2-diol

✍ Scribed by M. Sepulchre; N. Spassky


Publisher
Springer
Year
1985
Tongue
English
Weight
258 KB
Volume
13
Category
Article
ISSN
0170-0839

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## Abstract An economic and practical method for preparing enantiomerically pure [1,1′‐binaphthalene]‐2,2′‐diols is reported. Thus, a condensate of __threo__‐(1__S__,2__S__)‐2‐amino‐1‐(4‐nitrophenyl)propane‐1,3‐diol and cyclohexanone (CHANP) was used as a resolving agent. A 2 : 1 : 1 mixture of rac