Polymerization of phenylacetylene catalysed by cyclopentadienylnickel complexes
โ Scribed by William E. Douglas
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 42 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0268-2605
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Some new Rh(1) and Ir(1) complexes of the types [(COD)M(LL)]ClO, and [(COD)MCI], [COD = cyclooctadiene; M = Rh, Ir; LL = 1,l'-bis(dipheny1phosphino)ferrocene (DPPF), 1 -diphenylphosphino-2-(N,N-dimethylamino)methylferrocene (FcNP), 1,6-diferrocenyl-2,5diazahexane (FcNN)] were prepared, and their cat
Catalysis by insoluble polymer Cu complexes was studied for the oxidative polymerization of 2,6-dimethylphenol. The polymerization was heterogeneously catalysed by the insoluble complex. The catalyst was readily recovered by filtration and could be re-used. Compared with the homogeneous system, the