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Oxidative polymerization of 2,6-dimethylphenol catalysed by insoluble polymer copper complexes

✍ Scribed by H. Nishide; Y. Suzuki; E. Tsuchida

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
331 KB
Volume
17
Category
Article
ISSN
0014-3057

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✦ Synopsis

Catalysis by insoluble polymer Cu complexes was studied for the oxidative polymerization of 2,6-dimethylphenol. The polymerization was heterogeneously catalysed by the insoluble complex. The catalyst was readily recovered by filtration and could be re-used. Compared with the homogeneous system, the catalytic activity and the molecular weight of the produced polymer were lower for the insoluble polymer Cu complex because of steric hindrance, low flexibility of the ligand part and low concentration of the effective copper ion.

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