✦ LIBER ✦

Polymerization of phenylacetylene by hafnocene dichloride/RxAlCl3−x catalytic systems

✍ Scribed by Michael G. Siskos; Efthymios P. Bokaris; Antonios K. Zarkadis; Georgia Kyriakakou

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 271 KB
Volume: 28
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(92)90066-b

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✦ Synopsis

AMtract--The polymerization of phenylacetylene was investigated using the homogeneous catalysts Cp2 HfCI 2/R~ AIC13 _~. The reaction was performed in hydrocarbon and chlorinated hydrocarbon solvents at 0-aS0 °. In all cases, the polymers were coloured, soluble, polyconjugated and paramagnetic; they were characterized by i.r., tH-NMR, u.v.-visible and ESR spectroscopy.

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