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Polymerization of phenylacetylene by an olefin metathesis catalyst

✍ Scribed by Marijo Clark; Michael F. Farona


Publisher
Springer
Year
1982
Tongue
English
Weight
210 KB
Volume
7
Category
Article
ISSN
0170-0839

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On the mechanism of olefin polymerizatio
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## Abstract Ethylene polymerizations and norbornene oligomerizations catalysed by Cp~2~Ti^13^CH~3~Cl/MAO (Cp: cyclopentadienyl; MAO: methylaluminoxane) mixtures have been carried out at different temperatures (from ‐20Β°C to 20Β°C), in order to test the validity of carbene mechanisms in α‐olefin poly

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A "well-defined" alkylidcne complex of the type Mo(CHCMc2Ph)(N-2,6-i-Pr2C6H3)[OCMe(CF3)2] 2 has proven to be a useful initiator in catalytic olefin metathesis reactions of interest to organic chemists. A variety of related molybdenum imido alkylidene complexes can be prepared readily from a common p