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Homopolymerization of cyclic olefins by a molybdenum olefin metathesis catalyst

✍ Scribed by Jay A. Johnston; Michael F. Farona


Publisher
Springer
Year
1991
Tongue
English
Weight
187 KB
Volume
25
Category
Article
ISSN
0170-0839

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A "well-defined" alkylidcne complex of the type Mo(CHCMc2Ph)(N-2,6-i-Pr2C6H3)[OCMe(CF3)2] 2 has proven to be a useful initiator in catalytic olefin metathesis reactions of interest to organic chemists. A variety of related molybdenum imido alkylidene complexes can be prepared readily from a common p

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Catalytic properties of dimeric molybdenum(VI) triketonates were compared to those of MoO,(acac), in the epoxidation reaction of cyclooctene and 1,5cyclooctadiene with tertiary butyl hydroperoxide. Studies of the reaction at a molar ratio of olefin:TBHP:catalyst = l:l:O.OOl for the monoolefin and 1: