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Polymerization of N,N′-methylenebisacrylamide initiated by two new redox systems involving acidic permanganate

✍ Scribed by A. Gopalan; S. Paulrajan; K. Venkatarao; N.R. Subbaratnam

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
302 KB
Volume
19
Category
Article
ISSN
0014-3057

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✦ Synopsis

Two new redox systems, viz. KMnO 4 with ethyleneglycol and KMnO 4 with thioglycollic acid, have been used as initiators for the polymerization of the divinyl monomer, N,N'-methylenebisacrylamide. The initiating radical is formed when a monomer-Mn 3+ complex interacts with the redox complex. An intramolecular cyclization prior to propagation is involved in the mechanism suggested to explain the kinetics. The higher rate of polymerization for this monomer, when compared with acrylamide and methacrylamide, gives added evidence for this new type of propagation.

📜 SIMILAR VOLUMES

Kinetics of polymerization of N,N-methyl
Kinetics of polymerization of N,N-methylenebisacrylamide initiated by KMnO4-H2C2O4 redox system
✍ A. Gopalan; P. Venuvanalingam; S.P. Manickam; K. Venkatarao; N.R. Subbaratnam 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 272 KB

A kinetic study of the gel free polymerization of the divinyl monomer N,N'-methylenebisacrylamide has been made using permanganate-oxalic acid system as redox initiator; Rp is proportional to [monomer] 2, [KMnO4] and [H2C204] 0. A cyclopolymerization mechanism is proposed. A complex between monomer