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Kinetics of polymerization of N,N-methylenebisacrylamide initiated by KMnO4-H2C2O4 redox system

✍ Scribed by A. Gopalan; P. Venuvanalingam; S.P. Manickam; K. Venkatarao; N.R. Subbaratnam

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 272 KB
Volume: 18
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(82)90055-6

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✦ Synopsis

A kinetic study of the gel free polymerization of the divinyl monomer N,N'-methylenebisacrylamide has been made using permanganate-oxalic acid system as redox initiator; Rp is proportional to

[monomer] 2, [KMnO4] and [H2C204] 0. A cyclopolymerization mechanism is proposed. A complex between monomer and Mn 3 + participates, in addition to the complex [Mn(HC204)2] +.

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