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Polymerization of methyl methacrylate with nickelocene-methylaluminoxane catalyst

✍ Scribed by Kiyoshi Endo; Yoshihiro Yamanaka


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
39 KB
Volume
21
Category
Article
ISSN
1022-1336

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Polymerization of methyl methacrylate wi
✍ Endo, Kiyoshi; Inukai, Akihiro πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 97 KB πŸ‘ 1 views

Polymerization of methyl methacrylate (MMA) with nickel(II) acetylacetonate [Ni(acac) 2 ] in combination with methylaluminoxane (MAO) was investigated. Ni(acac) 2 was found to be an effective catalyst for the polymerization of MMA. From a kinetic study of the polymerization of MMA with the Ni(acac)

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Methyl methacrylate was polymerized with Cp 2 YCl(THF) or IVB group metallocene compounds (i.e., Cp 2 ZrCl 2 and Cp 2 HfCl 2 , etc.), in the presence of a Lewis acid like Zn(C 2 H 5 ) 2 . The Lewis acid was complexed with methyl methacrylate, which avoided the metallocene compounds being poisoned wi