𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polymerization of methyl methacrylate with Ni(acac)2-methylaluminoxane catalyst

✍ Scribed by Endo, Kiyoshi; Inukai, Akihiro

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
97 KB
Volume
49
Category
Article
ISSN
0959-8103

No coin nor oath required. For personal study only.

✦ Synopsis

Polymerization of methyl methacrylate (MMA) with nickel(II) acetylacetonate [Ni(acac) 2 ] in combination with methylaluminoxane (MAO) was investigated. Ni(acac) 2 was found to be an effective catalyst for the polymerization of MMA. From a kinetic study of the polymerization of MMA with the Ni(acac) 2 Β±MAO catalyst, the overall activation energy was estimated to be 15 kJmol Γ€1 . The polymerization rate (R p ) was expressed as follows: R p = k [MMA] 1.0 [Ni(acac) 2 Β±MAO] 0.6 (the MAO/Ni mole ratio was kept constant). The mechanism for the polymerization of vinyl monomers with the Ni(acac) 2 Β±MAO catalyst is discussed.

πŸ“œ SIMILAR VOLUMES

Copolymerization of styrene and butadien
Copolymerization of styrene and butadiene with Ni(acac)2-methylaluminoxane catalyst
✍ Kiyoshi Endo; Yuichi Matsuda πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 149 KB πŸ‘ 2 views

Copolymerization of styrene (St) and butadiene (Bd) with nickel(II) acetylacetonate [Ni(acac) 2 ]-methylaluminoxane (MAO) catalyst was investigated. Among the metal acetylacetonates [Mt(acac) x ] examined, Ni(acac) 2 showed a high activity for the copolymerization of St and Bd giving copolymers havi

Synthesis and properties of poly(methyl
Synthesis and properties of poly(methyl methacrylate)/clay nanocomposites prepared via in situ polymerization with Ni(acac)2 catalyst
✍ Liqiang Cui; Naresh H. Tarte; Seong Ihl Woo πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 250 KB πŸ‘ 2 views

## Abstract Poly(methyl methacrylate)(PMMA)/clay nano‐composites were successfully prepared by a new method, __in situ__ polymerization initiated with a nickel(II) acetylacetonate [Ni(acac)~2~] catalyst in combination with methylalumoxane (MAO). The synthesized PMMA/clay nanocomposites materials we