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Polymerization of Methacrylates in the Presence of Tetraphenylphosphonium Cation. 2. Evidence for Phosphorylide-Mediated Polymerizations

✍ Scribed by Baskaran, Durairaj; Müller, Axel H. E.; Kolshorn, Heinz; Zagala, Angela P.; Hogen-Esch, Thieo E.

Book ID
126150926
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
97 KB
Volume
30
Category
Article
ISSN
0024-9297

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Polymerization of 2-naphthyl methacrylat
Polymerization of 2-naphthyl methacrylate in the presence of electron acceptors
✍ H. Boudevska; M. Mintcheva 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 204 KB

The polymerization of 2-naphthyl methacrylate (NM) in toluene in the presence of tetracyanoethylene and picric acid was studied dilatometrically. The overall activation energy for the polymerization was calculated both in the absence and in the presence of electron acceptors. The results (13.7 kcal/