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Polymerization of liquid propylene with a 4th generation Ziegler–Natta catalyst—influence of temperature, hydrogen and monomer concentration and prepolymerization method on polymerization kinetics

✍ Scribed by Jochem T.M. Pater; Günter Weickert; Wim P.M. van Swaaij


Book ID
108311060
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
361 KB
Volume
57
Category
Article
ISSN
0009-2509

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Polymerization of liquid propylene with
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## Abstract Liquid propylene was polymerized in a 5‐L autoclave batch reactor using a commercially available TiCl~4~/MgCl~2~/Al(ethyl)~3~/DCPDMS Ziegler–Natta catalyst, with a phthalate ester as internal electron donor. The powders from these polymerizations were characterized using laser diffracti

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This paper presents an experimental kinetic study of the polymerization of propylene in liquid monomer with a high activity catalyst. The influences of the concentration of hydrogen and the molar ratios of the catalyst, cocatalyst, and electron donor on the activation period, the maximum activity, t