Kinetic study of a highly active MgCl2-supported Ziegler–Natta catalyst in liquid pool propylene polymerization. II. The influence of alkyl aluminum and alkoxysilane on catalyst activation and deactivation

Liquid-phase polymerization of propylene

Liquid-phase polymerization of propylene with a highly active Ziegler–Natta catalyst. Influence of hydrogen, cocatalyst, and electron donor on the reaction kinetics

✍ Job Jan C. Samson; Peter J. Bosman; Günter Weickert; K. Roel Westerterp 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 2 views

This paper presents an experimental kinetic study of the polymerization of propylene in liquid monomer with a high activity catalyst. The influences of the concentration of hydrogen and the molar ratios of the catalyst, cocatalyst, and electron donor on the activation period, the maximum activity, t