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Polymerization of lactide and related cyclic esters by discrete metal complexes

✍ Scribed by O'Keefe, Brendan J.; Hillmyer, Marc A.; Tolman, William B.


Book ID
111928194
Publisher
The Royal Society of Chemistry
Year
2001
Tongue
English
Weight
977 KB
Volume
15
Category
Article
ISSN
1472-7773

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Ring-opening polymerization of six-membe
✍ Yuushou Nakayama; Kenta Sasaki; Naoki Watanabe; Zhengguo Cai; Takeshi Shiono πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 341 KB

Catalytic behavior of tetrahydroborate complexes of rare earth metals, Ln(BH 4 ) 3 (THF) x (1: ), for ring-opening polymerization (ROP) of six-membered cyclic esters, d-valerolactone (VL) and D,L-lactide (D,L-LA), was studied. The controlled polymerization of VL with 1-6 proceeded in THF at 60 C. T