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Polymerization of acrylonitrile initiated by vanadium(V)–thiourea reaction

✍ Scribed by Jin-Yuan Wu; Chao-Xiong Yang

Book ID
105337502
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
237 KB
Volume
28
Category
Article
ISSN
0887-624X

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Kinetics of polymerization of acrylonitrile initiated by the Ce4+-thiourea redox system have been investigated at 10 °. The rate of monomer disappearance is proportional to (a) (monomer concentration)-", (b) thiourea concentration and, (c) (ceric ion concentration)-1. The rate of ceric disappearance