Polymerization of acrylonitrile initiated by organomagnesium compounds
β Scribed by Erussalimskii, B. L. ;Kulevskaya, I. V. ;Masurek, V. V.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 505 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0449-2994
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π SIMILAR VOLUMES
Kinetics of polymerization of acrylonitrile initiated by the Ce4+-thiourea redox system have been investigated at 10 Β°. The rate of monomer disappearance is proportional to (a) (monomer concentration)-", (b) thiourea concentration and, (c) (ceric ion concentration)-1. The rate of ceric disappearance
## Abstract The polymerization of acrylonitrile was studied with a peroxydiphosphateβascorbic acid redox system as the initiator. The rate of polymerization increased with increasing peroxydiphosphate concentration and the initiator exponent was computed to be 0.5. It also increased with increasing