Polymerization of acrylamide initiated by the redox system pinacolâMn(III)
✍ Scribed by Devi, N. Ganga; Mahadevan, V.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1972
- Tongue
- English
- Weight
- 265 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0887-6258
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## Abstract Polymerization of acrylamide initiated with a pinacol–ceric ion redox system was investigated. The polymer obtained was found to contain one cerium atom in a polymer molecule. It was considered that the cerium atom was introduced into the polymer molecule by the termination reaction as
Abstrae~Kinetics of oxidation of Tris-acetylacetonato V(III) by hydroxylamine in DMF and the polymerization of acrylamide have been investigated in the temperature range 20-30 C. The oxidation is a second order process with polymerization being initiated and terminated by the amino radicals. Rate an