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Redox polymerization of acrylamide initiated by the system V(III)(acac)3 hydroxylamine in dimethyl formamide

✍ Scribed by D.V.P.R. Vara Prasad; V. Mahadevan

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 193 KB
Volume: 17
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(81)90181-6

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✦ Synopsis

Abstrae~Kinetics of oxidation of Tris-acetylacetonato V(III) by hydroxylamine in DMF and the polymerization of acrylamide have been investigated in the temperature range 20-30 C. The oxidation is a second order process with polymerization being initiated and terminated by the amino radicals. Rate and thermodynamic data have been evaluated and their significance discussed.

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