๐”– Bobbio Scriptorium
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Polymerization of 2,6-Dimethylphenol with Mixed-Ligand Copper Complexes

โœ Scribed by Li, Kuo-Tseng; Shieh, Der-Chun


Book ID
127157329
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
539 KB
Volume
33
Category
Article
ISSN
0888-5885

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Catalysis by insoluble polymer Cu complexes was studied for the oxidative polymerization of 2,6-dimethylphenol. The polymerization was heterogeneously catalysed by the insoluble complex. The catalyst was readily recovered by filtration and could be re-used. Compared with the homogeneous system, the

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## ลฝ . ลฝ . Coupling polymerization of 2,6-dimethylphenol to poly 2,6-dimethyl-1,4-phenylene oxide PPO was carried out in an 1:1 aqueous-chloroform biphasic mixture using Cu-surface active ligand complex catalysts. Bidentate ligands were superior to monodentate ligands in promoting the oxidative co

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The oxidative coupling polymerization of 2,6-dimethylphenol (DMP) catalysed by copper(II) complexes of N-methylimidazole in toluene/iso-propanol (13/2v/v) or 1,2-dichlorobenzene/methanol (ODCB/MeOH) (13/2 v/v) was investigated. EPR spectra of these complexes indicated that the complex had a mononucl