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Polymerization of 2-(chlorinated methyl)-4-methylene-1,3-dioxolanes

โœ Scribed by Dietrich, Heinz J.


Publisher
Wiley (John Wiley & Sons)
Year
1968
Tongue
English
Weight
529 KB
Volume
6
Category
Article
ISSN
0449-296X

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The reaction of 2-methylene-l,3-dioxolanes and 2-methylene-1,3-oxazolidines with benzoyl peroxide (acceptor radical) and with N-ethylmaleimide (acceptor) was investigated. It was shown that benzoyl peroxide adds to monomers la and lb, giving the corresponding linear diester amides la and lb respecti

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Abstraet--2-(2',4'-Dichlorophenyl)-4-methylene-l,3-dioxolane was synthesized and polymerized by radical (AIBN and photochemically) and cationic (I 2, BF 3 . OEt2) routes. A polymerization mechanism is proposed based on the analysis of the resulting polymers.