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Polymerization of 1,3-dienes with iron complexes based catalysts: Influence of the ligand on catalyst activity and stereospecificity

โœ Scribed by Giovanni Ricci; Daniele Morganti; Anna Sommazzi; Roberto Santi; Francesco Masi


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
89 KB
Volume
204-205
Category
Article
ISSN
1381-1169

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The effects of phosphine ligands on the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate) 2 /AlEt 2 Cl/H 2 O were investigated. Although the polarizability of phosphine ligands, i.e. the ratio of the average dipole moment to the molecular volume, had moderate impact on 1,4-cis stereoregular