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Polymerization of 1,1,1-trifluoroacetone with aliphatic secondary amines. A proton and fluorine magnetic resonance investigation

✍ Scribed by M. M. Dhingra; K. R. Tatta

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
528 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The polymerization of 1,1,1‐trifluoroacetone with aliphatic secondary amines is reported. The polymerization product is found to be a mixture of four diastereoisomers of the cyclic trimer, the structure of which has been determined using proton and fluorine magnetic resonance spectroscopy. The proportions of the isomers have been estimated to be 70:19:8:3 from the ^19^F resonance spectrum. A comparative study of the reaction products of trifluoroacetone with metallic sodium and diethylamine is also discussed.

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