Polymerization by Oxidative Coupling. V. Catalytic Specificity in the Copper-Amine-catalyzed Oxidation of 2,6-Dimethylphenol 1a
✍ Scribed by Endres, G. F.; Hay, A. S.; Eustance, J. W.
- Book ID
- 118270955
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 731 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
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The oxidative coupling reaction of 2,6dimethylphenol (DMP) with H 2 O 2 catalyzed by four copper(II) complexes was investigated in Tris-HNO 3 buffer solution at 25 C. The kinetics of formation of diphenoquinone (DPQ, 4-(3,5-dimethyl-4-oxo-2,5-cyclohexadienylidene)-2,6-dimethyl-2,5-cyclohexadienone)
## Abstract Polyphenylene oxide (PPO) was prepared via oxidative coupling polymerization of 2,6‐dimethylphenol (DMP) catalyzed by copper salt. The ligand was a novel series of random copolymers (PSVP) of styrene and 4‐vinylpyridine prepared by reversible addition‐fragmentation chain transfer (RAFT)