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Polymerization and copolymerization of β-butyrolactone by aluminium compounds

✍ Scribed by N.C. Billingham; M.G. Proctor; J.D. Smith

Book ID
103223056
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
791 KB
Volume
341
Category
Article
ISSN
0022-328X

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Polymerization of methyl methacrylate by
Polymerization of methyl methacrylate by organometallic compounds—IV: Mechanism of polymerization and copolymerization initiated photochemically by triethyl-aluminium — monomer complexes
✍ P.E.M. Allen; B.A. Casey 📂 Article 📅 1970 🏛 Elsevier Science 🌐 English ⚖ 794 KB

~et--The photoinitiated polymerization of methyl methacrylate by triethyl-aluminium is shown to occur by a free radical mechanism, initiated by a photoexcited state of a 1 : I Wittig '-ate' complex between MMA and Et3AJ. A survey of related compounds shows that only monomers having an unsaturated g