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Polymerization of ɛ-Caprolactone and its Copolymerization with γ-Butyrolactone using Metal Complexes

✍ Scribed by Bhaw-Luximon, Archana; Jhurry, Dhanjay; Motala-Timol, Shaheen; Lochee, Yemanlall


Book ID
120506096
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
184 KB
Volume
231
Category
Article
ISSN
1022-1360

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## Abstract Copolymerization of γ‐butyrolactone (γBL) with ε‐caprolactone (εCL) initiated with aluminium isopropoxide trimer ([Al(O^i^Pr)~3~]~3~, (A~3~)) is described. Copolymers with molecular weights (__M__~n~) up to 3 · 10^4^ and containing up to 43 mol‐% repeating units derived from γBL are pre

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Copolymers of racemic b-butyrolactone (b-BL) with e-caprolactone (e-CL) (P(BL-co-CL)) and d-valerolactone (d-VL) (P(BL-co-VL)) were prepared by ring-opening polymerization reactions using the commercial aluminoxane catalyst tetraisobutyldialuminoxane (TIBAO). The yields, molecular weights, compositi