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Polymerisationsauslösung mit substituierten Ethanen, 10. Kinetik der Polymerisation von Styrol

✍ Scribed by Bledzki, Andrzej ;Braun, Dietrich ;Titzschkau, Klaus

Publisher
Wiley (John Wiley & Sons)
Year
1987
Weight
396 KB
Volume
188
Category
Article
ISSN
0025-116X

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✦ Synopsis

The rate of the free radical polymerization of styrene with substituted ethanes as initiators is characterized by a competition of "normal" and primary radical termination. With decreasing initiator concentration the reaction order with respect to monomer and initiator changes in favour of a normal termination. The kinetics of this polymerization process is derived and compared with experimental results.

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