In the layer structure of the title polymeric complex, {[Ag 2 (C 7 H 5 O 6 S) 2 (H 2 O) 3 ]ÁH 2 O} n , both substituted benzenesulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a " 4 -bonding mode. The two symmetr
Polymeric triaquabis(μ3-3-carboxybenzenesulfonato)barium(II)
✍ Scribed by Gao, Shan ;Zhu, Zhi-Biao ;Huo, Li-Hua ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 204 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The Ba atom in the title polymeric compound, poly [[triaquabarium(II)
exists in a nine-coordinate tricapped trigonal prismatic geometry; the dianionic units engage in 3 -bridging, giving a three-dimensional network. The crystal packing network is dominated by hydrogen bonds.
📜 SIMILAR VOLUMES
The Cu atom in the title compound, [Cu(C 7 H 5 O 6 S)-(C 10 H 8 N 2 )](C 7 H 5 O 6 S), is chelated by the two N-heterocycles and is covalently bonded to the sulfonate O atom of the sulfosalicylate ion in a trigonal±bipyramidal geometry. The uncoordinated sulfosalicylate anion interacts with adjacent
In the title compound, [Gd 2 (C 8 H 4 O 4 ) 2 (C 8 H 5 O 4 ) 2 (H 2 O)]ÁH 2 O, the Gd III ions are nine-coordinated and linked by carboxylate O bridges, giving rise to right-and left-handed inorganic helical chains. The crystal structure is stabilized by intra-and intermolecular O-HÁ Á ÁO hydrogen b
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.026 wR factor = 0.068 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.