Polymeric Tin(II) Complexes with Dibasic Nitrogen-Containing Organic Cations. Synthesis and Crystal Structure of (C10H10N2)0.5[SnF(SO4]
β Scribed by D. G. Detkov; Yu. E. Gorbunova; A. S. Kazarinova; Yu. N. Mikhailov; Yu. V. Kokunov
- Book ID
- 111544413
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2003
- Tongue
- English
- Weight
- 100 KB
- Volume
- 29
- Category
- Article
- ISSN
- 1070-3284
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π SIMILAR VOLUMES
Using 1, 4, 8, 11-tetraazacyclotetradecane (cyclam) as a template, a new layered zinc phosphate Zn 4 (PO 4 ) 2 (HPO 4 ) 2 ' 0.5(C 10 H 28 N 4 ) ' 2H 2 O (de5ned as ZnPO-cyclam) with 12-ring cavities was synthesized under hydrothermal conditions in a molar ratio ZnO:P 2 O 5 :cyclam:H 2 O β«Ψβ¬ 1:2.2:0.
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Γ , b = 107.105(3)Β°,