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Polymeric Rhodium-Containing Catalysts in Olefin Hydroformylation

✍ Scribed by E. V. Slivinskii; N. V. Kolesnichenko

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Hydroformylation of Olefins in the Presence of Rhodium Catalysts Immobilized on Polymeric Pyrrolidinopyridines. -The hydroformylation of olefins in the presence of catalytic systems based on RhCl3 and polymeric pyrrolidinopyridine is studied. This thermostable catalyst system is shown to be mo

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Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119Β°, respectively, are suited for this.