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Polymeric Peroxide of 2,5-Dimethyl-2,4-hexadiene and a New Selective Reduction of Its Peroxide Linkage

โœ Scribed by Griesbaum, Karl; Oswald, Alexis A.; Naegele, Walter


Book ID
126325017
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
688 KB
Volume
29
Category
Article
ISSN
0022-3263

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Stereoisomeric 2,5-Dimethyl-2,3:4,5-diox
โœ Dr. G. Bernhardt; Prof. Dr. F. Korte ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 237 KB ๐Ÿ‘ 1 views

The [Co(PF3)4]0 anion can be precipitated from aqueous solutions with voluminous cations. During the conversion of HCo(PF3)d into [Co(PF3)4]0, a bathochroniic shift of the P-F valence vibrations is observed which is probably due to a reduction in the double-bond character of the P-F bond. At PF3-pr